钌催化的二烯丙基硅烷与缺电子烯烃之间的交叉复分解反应。
Ruthenium-catalyzed cross-metathesis between diallylsilanes and electron-deficient olefins.
作者信息
BouzBouz Samir, Boulard Lucie, Cossy Janine
机构信息
Laboratoire de Chimie Organique, ESPCI, CNRS, 10 rue Vauquelin, 75231 Paris Cedex 05, France.
出版信息
Org Lett. 2007 Sep 13;9(19):3765-8. doi: 10.1021/ol0712632. Epub 2007 Aug 17.
PMID:17705394
Abstract
Diallysilanes can be selectively coupled with electron-deficient olefins under cross-metathesis (CM) conditions using the Hoveyda-Grubbs catalyst to produce mono- and/or bis-CM compounds in good yield. The formation of the mono- and the bis-CM compounds depends on the nature of the electron-deficient olefin.
摘要
在交叉复分解（CM）条件下，使用霍维达-格鲁布斯催化剂，二烯基硅烷可与缺电子烯烃选择性偶联，以良好的产率生成单和/或双CM化合物。单CM化合物和双CM化合物的形成取决于缺电子烯烃的性质。
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