Enantioselective synthesis of P-stereogenic phosphinates and phosphine oxides by molybdenum-catalyzed asymmetric ring-closing metathesis.
作者信息
Harvey James Stephen, Malcolmson Steven J, Dunne Katherine S, Meek Simon J, Thompson Amber L, Schrock Richard R, Hoveyda Amir H, Gouverneur Véronique
机构信息
Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford, OX1 3TA, UK.
出版信息
Angew Chem Int Ed Engl. 2009;48(4):762-6. doi: 10.1002/anie.200805066.
Abstract
摘要
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Enantioselective synthesis of P-stereogenic phosphinates and phosphine oxides by molybdenum-catalyzed asymmetric ring-closing metathesis.钼催化不对称闭环复分解反应对P-手性次膦酸酯和氧化膦的对映选择性合成
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本文引用的文献
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Molybdenum Imido Alkylidene Metathesis Catalysts that Contain Electron Withdrawing Biphenolates or Binaphtholates.含有吸电子联苯酚盐或联萘酚盐的钼亚胺基亚烷基复分解催化剂。
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Catalytic asymmetric deprotonation of phosphine boranes and sulfides as a route to P-stereogenic compounds.磷化硼烷和硫化物的催化不对称去质子化反应：通往P-立体异构化合物的一条途径
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Catalytic asymmetric synthesis of chiral phosphanes.手性膦的催化不对称合成。
Chemistry. 2008;14(24):7108-17. doi: 10.1002/chem.200800267.
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Enantioselective synthesis of P-stereogenic alkynylphosphine oxides by Rh-catalyzed [2+2+2] cycloaddition.通过铑催化的[2+2+2]环加成反应对P-手性炔基氧化膦进行对映选择性合成。
Angew Chem Int Ed Engl. 2008;47(18):3410-3. doi: 10.1002/anie.200800144.
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Pd-catalyzed dynamic kinetic enantioselective arylation of silylphosphines.钯催化的甲硅烷基膦的动态动力学对映选择性芳基化反应。
J Am Chem Soc. 2007 Dec 12;129(49):15122-3. doi: 10.1021/ja076457r. Epub 2007 Nov 16.
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The remarkable metal-catalysed olefin metathesis reaction.卓越的金属催化烯烃复分解反应。
Nature. 2007 Nov 8;450(7167):243-51. doi: 10.1038/nature06351.
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Ruthenium-catalyzed cross-metathesis between diallylsilanes and electron-deficient olefins.钌催化的二烯丙基硅烷与缺电子烯烃之间的交叉复分解反应。
Org Lett. 2007 Sep 13;9(19):3765-8. doi: 10.1021/ol0712632. Epub 2007 Aug 17.
8
Palladium-catalyzed asymmetric phosphination. Scope, mechanism, and origin of enantioselectivity.钯催化的不对称膦化反应。范围、机理及对映选择性的起源。
J Am Chem Soc. 2007 May 30;129(21):6847-58. doi: 10.1021/ja070225a. Epub 2007 May 3.
9
Enantioselective synthesis of P-stereogenic benzophospholanes via palladium-catalyzed intramolecular cyclization.通过钯催化的分子内环化反应对P-手性苯并膦烷进行对映选择性合成。
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10
Pallado-catalysed hydrophosphination of alkynes: access to enantio-enriched P-stereogenic vinyl phosphine-boranes.钯催化的炔烃氢膦化反应：获得对映体富集的P-手性乙烯基膦硼烷。
Chem Commun (Camb). 2006 Aug 14(30):3249-51. doi: 10.1039/b607434k. Epub 2006 Jun 26.
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