Lithium dimer formation in the Li-conducting garnets Li(5+x)Ba(x)La(3-x)Ta2O12 (0 < x < or =1.6).

作者信息

O'Callaghan Michael P, Cussen Edmund J

机构信息

WestCHEM, Department of Pure and Applied Chemistry, Thomas Graham Building, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, Scotland.

出版信息

Chem Commun (Camb). 2007 May 28(20):2048-50. doi: 10.1039/b700369b.

The garnet system Li(5+x)Ba(x)La(3-x)Ta2O12 shows an unprecedented Li+ content (x < or = 1.6) and short Li-Li distances of ca 2.44 A between majority occupied sites suggesting that the high Li+ mobility requires a complex cooperative mechanism.