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小分子金属簇的催化作用。

Catalysis by small metal clusters.

出版信息

Science. 1979 Sep 21;205(4412):1213-20. doi: 10.1126/science.205.4412.1213.

DOI:10.1126/science.205.4412.1213
PMID:17750133
Abstract

Experimental and theoretical studies of small clusters of metal atoms are aimed at revealing how properties change in the ultrafinely divided state. Thermodynamic, electronic, and structural features can be size-dependent and may be involved in determining the activity of small-particle catalysts. Correlations between these properties give indications of the features important in catalysis.

摘要

实验和理论研究金属原子的小簇旨在揭示在超细分散状态下性质如何变化。热力学、电子和结构特征可能随尺寸而变化,并可能参与决定小颗粒催化剂的活性。这些性质之间的相关性给出了在催化中重要的特征的指示。

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