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可生物降解/可降解塑料材料在需氧和厌氧条件下的生物降解性。

Biodegradability of biodegradable/degradable plastic materials under aerobic and anaerobic conditions.

作者信息

Mohee R, Unmar G D, Mudhoo A, Khadoo P

机构信息

Department of Chemical and Environmental Engineering, Faculty of Engineering, University of Mauritius, Réduit, Mauritius.

出版信息

Waste Manag. 2008;28(9):1624-9. doi: 10.1016/j.wasman.2007.07.003. Epub 2007 Sep 10.

Abstract

A study was conducted on two types of plastic materials, Mater-Bi Novamont (MB) and Environmental Product Inc. (EPI), to assess their biodegradability under aerobic and anaerobic conditions. For aerobic conditions, organic fractions of municipal solid wastes were composted. For the anaerobic process, anaerobic inoculum from a wastewater treatment plant was used. Cellulose filter papers (CFP) were used as a positive control for both mediums. The composting process was monitored in terms of temperature, moisture and volatile solids and the biodegradation of the samples were monitored in terms of mass loss. Monitoring results showed a biodegradation of 27.1% on a dry basis for MB plastic within a period of 72 days of composting. Biodegradability under an anaerobic environment was monitored in terms of biogas production. A cumulative methane gas production of 245 ml was obtained for MB, which showed good degradation as compared to CFP (246.8 ml). However, EPI plastic showed a cumulative methane value of 7.6 ml for a period of 32 days, which was close to the blank (4.0 ml). The EPI plastic did not biodegrade under either condition. The cumulative carbon dioxide evolution after 32 days was as follows: CFP 4.406 cm3, MB 2.198 cm3 and EPI 1.328 cm3. The cumulative level of CO2 varying with time fitted sigmoid type curves with R2 values of 0.996, 0.996 and 0.995 for CFP, MB and EPI, respectively.

摘要

对两种塑料材料,即诺维信公司的 Mater-Bi(MB)和环境产品公司(EPI)进行了一项研究,以评估它们在有氧和厌氧条件下的生物降解性。对于有氧条件,城市固体废物的有机部分进行了堆肥处理。对于厌氧过程,使用了来自污水处理厂的厌氧接种物。纤维素滤纸(CFP)用作两种介质的阳性对照。堆肥过程通过温度、湿度和挥发性固体进行监测,样品的生物降解通过质量损失进行监测。监测结果表明,在堆肥72天内,MB塑料在干基上的生物降解率为27.1%。在厌氧环境下的生物降解性通过沼气产量进行监测。MB的累计甲烷产量为245毫升,与CFP(246.8毫升)相比,显示出良好的降解效果。然而,EPI塑料在32天内的累计甲烷值为7.6毫升,接近空白值(4.0毫升)。EPI塑料在两种条件下均未发生生物降解。32天后的累计二氧化碳释放量如下:CFP为4.406立方厘米,MB为2.198立方厘米,EPI为1.328立方厘米。CFP、MB和EPI的二氧化碳累计水平随时间变化拟合为S形曲线,R2值分别为0.996、0.996和0.995。

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