Chen Rongsheng, Cheng Han, Wu Wenzhan, Ai Xiaoni, Huang Weihua, Wang Zongli, Cheng Jieke
Department of Chemistry, Wuhan University, Wuhan 430072, P. R. China.
Electrophoresis. 2007 Oct;28(19):3347-61. doi: 10.1002/elps.200700249.
Capillary electrophoresis has become a widely useful analytical technology. Amperometric detection is extensively employed in capillary electrophoresis for its many inherent virtues, such as rapid response, remarkable sensitivity, and low cost of both detectors and instrumentations. Analysis of inorganic and small organic ions by capillary electrophoresis is an important research field. This review focuses on the recent developments of capillary electrophoresis coupled with amperometric detection for analysis of inorganic and small organic ions. Advancements in electrophoresis separation modes, amperometric detection modes, working electrodes, and applications of inorganic ions, amino acids, phenols, and amines are discussed.
毛细管电泳已成为一种广泛应用的分析技术。安培检测因其诸多固有优点，如响应迅速、灵敏度高以及检测器和仪器成本低等，而在毛细管电泳中得到广泛应用。利用毛细管电泳分析无机离子和小有机离子是一个重要的研究领域。本综述重点关注毛细管电泳与安培检测联用在分析无机离子和小有机离子方面的最新进展。讨论了电泳分离模式、安培检测模式、工作电极以及无机离子、氨基酸、酚类和胺类的应用方面的进展。
