Astumian R Dean
University of Maine, Orono, Maine 04469, USA.
Phys Rev E Stat Nonlin Soft Matter Phys. 2007 Aug;76(2 Pt 1):020102. doi: 10.1103/PhysRevE.76.020102. Epub 2007 Aug 27.
A Brownian motor is a nanoscale or molecular device that combines the effects of thermal noise, spatial or temporal asymmetry, and directionless input energy to drive directed motion. Because of the input energy, Brownian motors function away from thermodynamic equilibrium and concepts such as linear response theory, fluctuation dissipation relations, and detailed balance do not apply. The generalized fluctuation-dissipation relation, however, states that even under strongly thermodynamically nonequilibrium conditions the ratio of the probability of a transition to the probability of the time reverse of that transition is the exponential of the change in the internal energy of the system due to the transition. Here, we derive an extension of the generalized fluctuation dissipation theorem for a Brownian motor for the ratio between the probability for the motor to take a forward step and the probability to take a backward step.
布朗运动马达是一种纳米级或分子级装置,它结合了热噪声、空间或时间不对称性以及无定向输入能量的效应来驱动定向运动。由于输入能量的存在,布朗运动马达在远离热力学平衡的条件下运行,诸如线性响应理论、涨落耗散关系和细致平衡等概念并不适用。然而,广义涨落耗散关系表明,即使在强烈的热力学非平衡条件下,一个转变的概率与该转变的时间反演的概率之比,是由于该转变导致的系统内能变化的指数。在此,我们推导出了一个适用于布朗运动马达的广义涨落耗散定理的扩展形式,用于描述马达向前步进概率与向后步进概率之间的比率。