基于具有纳米尺寸空腔的金属有机多面体作为超分子构建单元的多孔金属有机框架：[Cu6L8]12+纳米笼的双贯穿原始立方网络。
Porous metal-organic frameworks based on metal-organic polyhedra with nanosized cavities as supramolecular building blocks: two-fold interpenetrating primitive cubic networks of [Cu6L8]12+ nanocages.
作者信息
Park Jaejoon, Hong Seunghee, Moon Dohyun, Park Mira, Lee Kyungjin, Kang Sangmi, Zou Yang, John Rohith P, Kim Ghyung Hwa, Lah Myoung Soo
机构信息
Department of Chemistry and Applied Chemistry, College of Science and Technology, Hanyang University, Ansan, Kyunggi-Do 426-791, Korea.
出版信息
Inorg Chem. 2007 Nov 26;46(24):10208-13. doi: 10.1021/ic7013623. Epub 2007 Oct 31.
Discrete metal-organic polyhedra (MOP) with nanosized cavities and/or clusters of MOP could be prepared when C3-symmetric facial ligands and a potential hexatopic Cu(II) ion are combined in the presence of perchlorate as a weak linker, while similar reaction conditions in the presence of a nitrate linker led to extended metal-organic frameworks made of MOP as supramolecular building blocks.
当具有C3对称性的面式配体与潜在的六齿铜（II）离子在作为弱连接体的高氯酸盐存在下结合时，可以制备出具有纳米尺寸空腔和/或金属有机多面体簇的离散金属有机多面体（MOP），而在硝酸盐连接体存在下的类似反应条件则导致由MOP作为超分子结构单元构成的扩展金属有机框架。
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