阳离子钯（II）催化2-酰基芳基硼酸与取代炔烃的高度对映选择性[3+2]环化反应。
Cationic palladium(II)-catalyzed highly enantioselective [3+2] annulation of 2-acylarylboronic acids with substituted alkynes.
作者信息
Yang Miao, Zhang Xumu, Lu Xiyan
机构信息
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 354 Fenglin Road, Shanghai 200032, China.
出版信息
Org Lett. 2007 Nov 22;9(24):5131-3. doi: 10.1021/ol702503e. Epub 2007 Nov 2.
PMID:17975925
Abstract
A cationic palladium(II)-catalyzed enantioselective tandem [3+2] annulation of 2-acylarylboronic acids with substituted alkynes to yield optically active 1-indenols was developed in high yields and excellent enantioselectivities.
摘要
开发了一种阳离子钯（II）催化的2-酰基芳基硼酸与取代炔烃的对映选择性串联[3+2]环化反应，以高收率和优异的对映选择性生成光学活性的1-茚醇。
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