Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China.
Chem Commun (Camb). 2010 May 7;46(17):2950-2. doi: 10.1039/b926763h. Epub 2010 Mar 8.
A novel and efficient route for the synthesis of 1-methyleneindenes via palladium-catalyzed tandem reactions of 1-(2,2-dibromovinyl)-2-alkynylbenzene with arylboronic acids is described. This reaction proceeded under mild conditions with high efficiency and excellent selectivity.
一种通过钯催化 1-(2,2-二溴乙烯基)-2-炔基苯与芳基硼酸的串联反应合成 1-亚甲基茚的新颖高效方法得到了描述。该反应在温和的条件下以高效率和优异的选择性进行。