阳离子钯（II）催化的邻硼酸酯取代肉桂酮与内炔的高对映选择性串联反应：一种简便合成光学活性茚的方法。
Cationic palladium(II)-catalyzed highly enantioselective tandem reactions of ortho-boronate-substituted cinnamic ketones and internal alkynes: a convenient synthesis of optically active indenes.
作者信息
Zhou Feng, Yang Miao, Lu Xiyan
机构信息
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 345 Lingling Road, Shanghai 200032, China.
出版信息
Org Lett. 2009 Mar 19;11(6):1405-8. doi: 10.1021/ol9001015.
PMID:19243157
Abstract
Cationic palladium(II)-catalyzed tandem reactions of ortho-boronate-substituted cinnamic ketones and internal alkynes to yield optically active indenes were developed in high yields and good enantioselectivities.
摘要
开发了阳离子钯（II）催化的邻硼酸酯取代的肉桂酮与内炔的串联反应，以高产率和良好的对映选择性生成光学活性茚。
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