Nehru Kasi, Kim Soo Jeong, Kim In Young, Seo Mi Sook, Kim Youngmee, Kim Sung-Jin, Kim Jinheung, Nam Wonwoo
Department of Chemistry, Division of Nano Sciences, and Center for Biomimetic Systems, Ewha Womans University, Seoul, Korea.
Chem Commun (Camb). 2007 Nov 28(44):4623-5. doi: 10.1039/b708976g. Epub 2007 Sep 20.
A non-heme manganese(II) complex shows a high catalytic activity in the epoxidation of olefins by iodosyl benzene and in the oxidation of olefins, alcohols and alkanes by peracetic acid; a mechanism involving metal-based oxidants is proposed for the oxidation reactions.
一种非血红素锰（II）配合物在由碘苯进行的烯烃环氧化反应以及由过氧乙酸进行的烯烃、醇和烷烃氧化反应中表现出高催化活性；针对这些氧化反应提出了一种涉及金属基氧化剂的机理。
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