高效的[双（亚氨基）吡啶-铁]催化的烷烃氧化反应。
Efficient [bis(imino)pyridine-iron]-catalyzed oxidation of alkanes.
作者信息
Tang Jinkui, Gamez Patrick, Reedijk Jan
机构信息
Leiden Institute of Chemistry, Leiden University, P. O. Box 9502, 2300 RA Leiden, The Netherlands.
出版信息
Dalton Trans. 2007 Nov 7(41):4644-6. doi: 10.1039/b712849p. Epub 2007 Sep 3.
DOI:10.1039/b712849p
PMID:17940643
Abstract
A [bis(imino)pyridine-iron(II)] complex efficiently catalyses the oxidation of C(sp3)-H bonds by dihydrogen peroxide, through the attack of the alkyl substrate by hydroxyl radicals.
摘要
一种[双（亚氨基）吡啶-铁（II）]配合物通过羟基自由基对烷基底物的攻击，有效地催化了过氧化氢对C(sp3)-H键的氧化反应。
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