自终止氧化自由基环化反应
Self-terminating, oxidative radical cyclizations.
作者信息
Dreessen Tim, Jargstorff Christian, Lietzau Lars, Plath Christian, Stademann Arne, Wille Uta
机构信息
Institut für Organische Chemie, Universität Kiel, Olshausenstr, 40, 24098 Kiel, Germany.
出版信息
Molecules. 2004 May 31;9(6):480-97. doi: 10.3390/90600480.
Abstract
The recently discovered novel concept of self-terminating, oxidative radical cyclizations, through which alkynes can be converted into carbonyl compounds under very mild reaction conditions using O-centered inorganic and organic radicals as oxidants, is described.
摘要
本文描述了最近发现的一种新颖的自终止氧化自由基环化概念，通过该概念，炔烃在非常温和的反应条件下，以氧中心的无机和有机自由基作为氧化剂，可以转化为羰基化合物。
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