吡喃和吡喃酮天然产物的合成。
Synthesis of pyran and pyranone natural products.
作者信息
Donner Christopher D, Gill Melvyn, Tewierik Leonie M
机构信息
School of Chemistry, The University of Melbourne, Parkville, Victoria 3010, Australia.
出版信息
Molecules. 2004 May 31;9(6):498-512. doi: 10.3390/90600498.
Abstract
An overview of the synthesis of the fungal metabolites (+)-dermolactone, (-)- semixanthomegnin, (+)- and (-)-mellein, (-)-ochratoxin alpha, (-)-(1R,3S)-thysanone, the enantiopure ventiloquinones L, E and G, and 8-desmethyleleutherin from a common chiral intermediate, is presented. Further methodology leading potentially toward extended quinones such as (3S,3'S)-xylindein is also outlined.
摘要
本文概述了从一个常见的手性中间体合成真菌代谢产物（+）-皮肤内酯、（-）-半黄麦角硫因、（+）-和（-）-水芹烯内酯、（-）-赭曲霉毒素α、（-）-（1R，3S）-桑酮、对映体纯的通风醌L、E和G以及8-去甲基刺蒺藜素的方法。还概述了可能通向扩展醌类如（3S，3'S）-木林菌素的进一步方法。
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Absolute configuration and tautomeric structure of xylindein, a blue-green pigment of Chlorociboria species.绿核菌属物种的蓝绿色色素木层孔菌素的绝对构型和互变异构结构。
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