二氟化氙引发的芳基碘化物还原消除反应：一种简便合成二氟钯（II）配合物的方法
Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes.
作者信息
Kaspi Ariela W, Yahav-Levi Anette, Goldberg Israel, Vigalok Arkadi
机构信息
School of Chemistry, The Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv, Israel.
出版信息
Inorg Chem. 2008 Jan 7;47(1):5-7. doi: 10.1021/ic701722f. Epub 2007 Dec 4.
PMID:18052157
Abstract
Palladium(II) aryliodo complexes bearing chelating diphosphine ligands react with XeF2, giving iodoarene and rare palladium(II) difluoro complexes. The reaction is general with regard to the aryl group, with even C6F5-I undergoing facile reductive elimination from a Pd center.
摘要
带有螯合二膦配体的钯（II）芳基碘配合物与XeF2反应，生成碘芳烃和罕见的钯（II）二氟配合物。该反应对于芳基具有普遍性，甚至C6F5-I也能从钯中心轻松进行还原消除反应。
Zotero 插件