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通过添加粉煤灰和石灰研究污水污泥的稳定化潜力。

Investigation of sewage sludge stabilization potential by the addition of fly ash and lime.

作者信息

Samaras P, Papadimitriou C A, Haritou I, Zouboulis A I

机构信息

Department of Pollution Control Technologies, Technological Educational Institute of West Macedonia, Koila, 50100 Kozani, Greece.

出版信息

J Hazard Mater. 2008 Jun 15;154(1-3):1052-9. doi: 10.1016/j.jhazmat.2007.11.012. Epub 2007 Nov 13.

Abstract

The aim of this work was the examination of stabilization potential of sewage sludge by the addition of fly ash and/or lime and the investigation of the effect of stabilization time on the properties of produced mixtures. Five samples were prepared by mixing fly ash, sewage sludge and lime in various ratios and the mixtures were stabilized for a period of 35 d. The addition of alkaline agents resulted in the increase of sample pH up to 12, the increase of total solids content to about 50% and the reduction of the organic fraction of the solids. The produced samples presented inhibition effects to seed germination and root length growth of three higher plants (one monocotyl and two dicotyls); however, samples with high sludge content resulted in negligible seed germination inhibition at prolonged stabilization times. The standard TCLP leaching procedure was applied in all the produced samples in order to evaluate the extraction potential of certain metallic elements; the content of metals in the eluates was varied, depending upon their speciation and form. Eluates presented significant inhibition to the marine photobacterium Vibrio fischeri bioluminescence, while the lowest inhibition was detected for the samples containing higher sludge content. These samples potentially could be applied as soil amendment, offering an efficient method for the combined utilization of two different solid wastes; however, low dosages of fly ash should be used for the production of a stabilized material presenting negligible effects with respect to its phytotoxic and ecotoxic properties.

摘要

这项工作的目的是研究添加粉煤灰和/或石灰对污泥的稳定化潜力,以及研究稳定化时间对所制备混合物性质的影响。通过将粉煤灰、污泥和石灰按不同比例混合制备了五个样品,并将混合物稳定化35天。添加碱性试剂导致样品pH值升高至12,总固体含量增加至约50%,固体有机部分减少。所制备的样品对三种高等植物(一种单子叶植物和两种双子叶植物)的种子萌发和根长生长呈现抑制作用;然而,污泥含量高的样品在延长稳定化时间后对种子萌发的抑制作用可忽略不计。对所有制备的样品采用标准TCLP浸出程序,以评估某些金属元素的提取潜力;洗脱液中金属的含量因它们的形态和形式而异。洗脱液对海洋发光细菌费氏弧菌的生物发光呈现显著抑制作用,而对污泥含量较高的样品检测到的抑制作用最低。这些样品有可能用作土壤改良剂,为两种不同固体废物的联合利用提供一种有效方法;然而,应使用低剂量的粉煤灰来生产一种稳定化材料,使其在植物毒性和生态毒性方面的影响可忽略不计。

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