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来自地中海(爱奥尼亚海)的小规格蓝鳍金枪鱼(金枪鱼)样本中的持久性有机污染物(多氯联苯和滴滴涕)

Persistent organic pollutants (PCBs and DDTs) in small size specimens of bluefin tuna (Thunnus thynnus) from the Mediterranean Sea (Ionian Sea).

作者信息

Storelli M M, Casalino E, Barone G, Marcotrigiano G O

机构信息

Pharmacological-Biological Department, Chemistry and Biochemistry Section, Veterinary Medicine Faculty, University of Bari- Strada Prov. le per Casamassima Km 3, Valenzano Ba, Italy.

出版信息

Environ Int. 2008 May;34(4):509-13. doi: 10.1016/j.envint.2007.11.006. Epub 2008 Mar 4.

Abstract

The concentration levels and pattern distribution of polychlorinated biphenyls (PCBs) and organochlorine pesticides (DDTs), were investigated in liver of small size specimens of bluefin tuna (Thunnus thynnus) from Mediterranean Sea (Ionian Sea). PCB concentrations (average: 526 ng g(-1) lipid wt) were comparable with DDT levels (average: 435 ng g(-1) lipid wt). The specific analysis of PCB congeners revealed a profile dominated by hexa-, penta- and heptachlorinated congeners, while among DDTs, the compounds with the higher concentration was p,p'-DDE, constituting 91.9% of the total DDT. The total 2,3,7,8-TCDD toxic equivalent (TEQs) of coplanar PCBs, including mono- and non-ortho congeners, was 0.55 pg g(-1) wet weight with. The congeners with highest TEQs values were non-ortho congeners followed by mono-ortho ones.

摘要

对来自地中海(爱奥尼亚海)的小规格蓝鳍金枪鱼(Thunnus thynnus)肝脏中多氯联苯(PCBs)和有机氯农药(DDTs)的浓度水平及模式分布进行了研究。多氯联苯的浓度(平均:526纳克/克脂质重量)与滴滴涕水平(平均:435纳克/克脂质重量)相当。多氯联苯同系物的具体分析显示,其分布特征以六氯、五氯和七氯同系物为主,而在滴滴涕中,浓度较高的化合物是p,p'-DDE,占总滴滴涕的91.9%。包括单邻位和非邻位同系物在内的共面多氯联苯的总2,3,7,8-四氯二苯并二恶英毒性当量(TEQs)为0.55皮克/克湿重。毒性当量值最高的同系物是非邻位同系物,其次是单邻位同系物。

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