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内陆和沿海克罗地亚的马鹿(Cervus elaphus L.)和黇鹿(Dama dama L.)中的有机氯化合物。

Organochlorine compounds in red deer (Cervus elaphus L.) and fallow deer (Dama dama L.) from inland and coastal Croatia.

机构信息

Institute for Medical Research and Occupational Health, Ksaverska cesta 2, PO Box 291, 10001 Zagreb, Croatia.

出版信息

Environ Monit Assess. 2012 Aug;184(8):5173-80. doi: 10.1007/s10661-011-2331-0. Epub 2011 Sep 9.

Abstract

Polychlorinated biphenyl (PCB) and organochlorine pesticide (OCP) levels in fat tissue of red and fallow deer (Cervus elaphus L. and Dama dama L.) from two inland and an Adriatic area were established. Of 17 analysed PCBs, PCB-28, PCB-138, PCB-153, PCB-180 and PCB-118 were found in all samples, whilst PCB-101 and PCB-170 were found in more than 50% of samples. They ranged between 0.03 and 5.98 ng g(-1) fat weight. Of seven analysed OCPs, HCB, γ-HCH and 1,1-dichloro-2,2-di(4-chlorophenyl)ethylene (DDE) were found in all samples, whilst β-HCH was found in more than 50% of samples. They ranged between 0.17 and 22.14 ng g(-1) fat weight. The dominating compounds were DDE, PCB-138, PCB153, PCB-118 and PCB-180. According to the Duncan multistage test, the levels of PCB-138, PCB-153, PCB 170 and PCB-180 were significantly higher in perirenal fat samples of specimens taken from the Adriatic area. DDE was significantly higher in the inland deer samples. Some species differences were determined and were mostly related to higher PCB and β-HCH levels in fallow deer samples and higher DDE levels in red deer samples. No sex difference was established. As for age, significantly higher levels of PCB-118 and PCB-52 were found in fawns.

摘要

检测了来自两个内陆地区和亚得里亚海地区的马鹿和梅花鹿(Cervus elaphus L. 和 Dama dama L.)脂肪组织中的多氯联苯(PCB)和有机氯农药(OCP)含量。在所分析的 17 种 PCB 中,所有样品中均发现了 PCB-28、PCB-138、PCB-153、PCB-180 和 PCB-118,而 PCB-101 和 PCB-170 则在超过 50%的样品中被发现。这些 PCB 的浓度范围为 0.03 至 5.98ng/g 脂肪重量。在所分析的 7 种 OCP 中,所有样品中均发现了 HCB、γ-六氯环己烷(γ-HCH)和 1,1-二氯-2,2-双(4-氯苯基)乙烯(DDE),而 β-六氯环己烷(β-HCH)则在超过 50%的样品中被发现。这些 OCP 的浓度范围为 0.17 至 22.14ng/g 脂肪重量。占主导地位的化合物为 DDE、PCB-138、PCB-153、PCB-118 和 PCB-180。根据邓肯多阶段测试,亚得里亚海地区采集的样本肾周脂肪中 PCB-138、PCB-153、PCB-170 和 PCB-180 的含量明显更高。内陆地区的鹿样本中 DDE 的含量明显更高。还确定了一些种间差异,这些差异主要与马鹿样本中更高的 PCB 和 β-HCH 水平以及梅花鹿样本中更高的 DDE 水平有关。没有发现性别差异。至于年龄,幼鹿样本中 PCB-118 和 PCB-52 的含量明显更高。

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