Li Jianfeng, Noll Bruce C, Scheidt W Robert
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556. E-mail:
Acta Crystallogr Sect E Struct Rep Online. 2007 Apr;E63(4):m1048-m1049. doi: 10.1107/S1600536807010689.
The Zn atom in the structure of the title compound, [ZnCl(2)(C(5)N(2)H(8))(2)], exhibits a distorted tetrahedral geometry and is coordinated by two Cl and two N atoms, with Zn-Cl distances of 2.2519 (2) and 2.2531 (2) Å, and Zn-N distances of 1.9998 (7) and 2.0087 (7) Å. The angles Cl-Zn-Cl and N-Zn-N are 114.742 (9) and 108.50 (3)°, respectively.
标题化合物[ZnCl₂(C₅N₂H₈)₂]结构中的锌原子呈现出扭曲的四面体几何构型,由两个氯原子和两个氮原子配位,Zn-Cl键长分别为2.2519(2) Å和2.2531(2) Å,Zn-N键长分别为1.9998(7) Å和2.0087(7) Å。Cl-Zn-Cl和N-Zn-N夹角分别为114.742(9)°和108.50(3)°。