二氯（6-甲基-2,2'-联吡啶-κN,N'）锌（II）
Dichlorido(6-methyl-2,2'-bipyridine-κN,N')zinc(II).
作者信息
Ahmadi Roya, Kalateh Khadijeh, Ebadi Amin, Amani Vahid, Khavasi Hamid Reza
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 13;64(Pt 10):m1266. doi: 10.1107/S1600536808028894.
Abstract
In the mol-ecule of the title compound, [ZnCl(2)(C(11)H(10)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the 6-methyl-2,2'-bipyridine ligand and by two Cl atoms. There are π-π contacts between the pyridine ring and the five-membered ring, and also between the pyridine rings, [centroid-centroid distances = 3.685 (3) and 3.757 (3) Å, respectively].
摘要
在标题化合物[ZnCl₂(C₁₁H₁₀N₂)]的分子中，Zn(II)原子通过来自6-甲基-2,2'-联吡啶配体的两个N原子和两个Cl原子以扭曲的四面体构型进行四配位。吡啶环与五元环之间以及吡啶环之间存在π-π接触，[质心-质心距离分别为3.685(3)和3.757(3) Å]。
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