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二氯（6-甲基-2,2'-联吡啶-κN,N'）锌（II）

Dichlorido(6-methyl-2,2'-bipyridine-κN,N')zinc(II).

作者信息

Ahmadi Roya, Kalateh Khadijeh, Ebadi Amin, Amani Vahid, Khavasi Hamid Reza

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 13;64(Pt 10):m1266. doi: 10.1107/S1600536808028894.

DOI:10.1107/S1600536808028894
PMID:21201019
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959229/
Abstract

In the mol-ecule of the title compound, [ZnCl(2)(C(11)H(10)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the 6-methyl-2,2'-bipyridine ligand and by two Cl atoms. There are π-π contacts between the pyridine ring and the five-membered ring, and also between the pyridine rings, [centroid-centroid distances = 3.685 (3) and 3.757 (3) Å, respectively].

摘要

在标题化合物[ZnCl₂(C₁₁H₁₀N₂)]的分子中，Zn(II)原子通过来自6-甲基-2,2'-联吡啶配体的两个N原子和两个Cl原子以扭曲的四面体构型进行四配位。吡啶环与五元环之间以及吡啶环之间存在π-π接触，[质心-质心距离分别为3.685(3)和3.757(3) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4135/2959229/b9d719b3598c/e-64-m1266-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4135/2959229/2e1c79fc3992/e-64-m1266-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4135/2959229/b9d719b3598c/e-64-m1266-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4135/2959229/2e1c79fc3992/e-64-m1266-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4135/2959229/b9d719b3598c/e-64-m1266-fig2.jpg

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