Wakamiya Atsushi, Mishima Kotaro, Ekawa Kanako, Yamaguchi Shigehiro
Department of Chemistry, Graduate School of Science, Nagoya University, and SORST, Japan Science and Technology Agency, Chikusa, Nagoya 464-8602, Japan.
Chem Commun (Camb). 2008 Feb 7(5):579-81. doi: 10.1039/b716107g. Epub 2007 Nov 23.
A synthetic route to a dibenzoborole, kinetically stabilized by the 2,4,6-tri-tert-butylphenyl group, was developed, and a series of pi-extended derivatives were synthesized, which show orange-red emissions and stable electrochemical redox properties.
开发了一种通往由2,4,6-三叔丁基苯基动力学稳定的二苯并硼杂环戊二烯的合成路线,并合成了一系列π-扩展衍生物,这些衍生物呈现橙红色发射和稳定的电化学氧化还原性质。