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动力学稳定的二苯并硼杂环戊二烯作为电子接受构建单元。

Kinetically stabilized dibenzoborole as an electron-accepting building unit.

作者信息

Wakamiya Atsushi, Mishima Kotaro, Ekawa Kanako, Yamaguchi Shigehiro

机构信息

Department of Chemistry, Graduate School of Science, Nagoya University, and SORST, Japan Science and Technology Agency, Chikusa, Nagoya 464-8602, Japan.

出版信息

Chem Commun (Camb). 2008 Feb 7(5):579-81. doi: 10.1039/b716107g. Epub 2007 Nov 23.

DOI:10.1039/b716107g
PMID:18209795
Abstract

A synthetic route to a dibenzoborole, kinetically stabilized by the 2,4,6-tri-tert-butylphenyl group, was developed, and a series of pi-extended derivatives were synthesized, which show orange-red emissions and stable electrochemical redox properties.

摘要

开发了一种通往由2,4,6-三叔丁基苯基动力学稳定的二苯并硼杂环戊二烯的合成路线,并合成了一系列π-扩展衍生物,这些衍生物呈现橙红色发射和稳定的电化学氧化还原性质。

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