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不同污水污泥与煤的共燃烧:非等温热重动力学分析

Co-combustion of different sewage sludge and coal: a non-isothermal thermogravimetric kinetic analysis.

作者信息

Otero M, Calvo L F, Gil M V, García A I, Morán A

机构信息

IRENA and Department of Chemical Engineering, University of León, Avenida de Portugal 41, 24071 León, Spain.

出版信息

Bioresour Technol. 2008 Sep;99(14):6311-9. doi: 10.1016/j.biortech.2007.12.011. Epub 2008 Feb 5.

Abstract

The kinetics of the combustion of coal, two different sewage sludge and their blends (containing different dried weight percentages of sewage sludge) was studied by simultaneous thermogravimetric analysis. Once the weight percentage of sludge in the blend was 10%, the effects on the combustion of coal were hardly noticeable in terms of weight loss. The Arrhenius activation energy corresponding to the co-combustion of the blends was evaluated by non-isothermal kinetic analysis. This showed that, though differences between coal and sewage sludge, the combustion of their blends kept kinetically alike to that of the coal. This work illustrates how thermogravimetric analysis may be used as an easy rapid tool to asses, not only mass loss, but also kinetics of the co-combustion of sewage sludge and coal blends.

摘要

通过同步热重分析研究了煤、两种不同的污水污泥及其混合物(含有不同干重百分比的污水污泥)的燃烧动力学。一旦混合物中污泥的重量百分比为10%,就重量损失而言,对煤燃烧的影响几乎不明显。通过非等温动力学分析评估了混合物共燃烧对应的阿伦尼乌斯活化能。结果表明,尽管煤和污水污泥之间存在差异,但它们混合物的燃烧在动力学上与煤的燃烧相似。这项工作说明了热重分析如何可作为一种简便快速的工具,不仅用于评估质量损失,还用于评估污水污泥与煤混合物的共燃烧动力学。

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