Pegau W S, Gray D, Zaneveld J R
Appl Opt. 1997 Aug 20;36(24):6035-46. doi: 10.1364/ao.36.006035.
We have measured the absorption coefficient of pure and salt water at 15 wavelengths in the visible and near-infrared regions of the spectrum using WETLabs nine-wavelength absorption and attenuation meters and a three-wavelength absorption meter. The water temperature was varied between 15 and 30 degrees C, and the salinity was varied between 0 and 38 PSU to study the effects of these parameters on the absorption coefficient of liquid water. In the near-infrared portion of the spectrum the absorption coefficient of water was confirmed to be highly dependent on temperature. In the visible region the temperature dependence was found to be less than 0.001 m-1 degrees C except for a small region around 610 nm. The same results were found for the temperature dependence of a saltwater solution. After accounting for index-of-refraction effects, the salinity dependence at visible wavelengths is negligible. Salinity does appear to be important in determining the absorption coefficient of water in the near-infrared region. At 715 nm, for example, the salinity dependence was -0.00027 m-1 /PSU. Field measurements support the temperature and salinity dependencies found in the laboratory both in the near infrared and at shorter wavelengths. To make estimates of the temperature dependence in wavelength regions for which we did not make measurements we used a series of Gaussian curves that were fit to the absorption spectrum in the visible region of the spectrum. The spectral dependence on temperature was then estimated based on multiplying the Gaussians by a fitting factor.
我们使用WETLabs九波长吸收和衰减仪以及三波长吸收仪,在光谱的可见光和近红外区域的15个波长处测量了纯水和盐水的吸收系数。水温在15至30摄氏度之间变化,盐度在0至38 PSU之间变化,以研究这些参数对液态水吸收系数的影响。在光谱的近红外部分,证实水的吸收系数高度依赖于温度。在可见光区域,除了610 nm附近的一个小区域外,温度依赖性小于0.001 m⁻¹℃。对于盐水溶液的温度依赖性也得到了相同的结果。在考虑折射指数效应后,可见光波长下的盐度依赖性可以忽略不计。盐度在确定近红外区域水的吸收系数方面似乎很重要。例如,在715 nm处,盐度依赖性为-0.00027 m⁻¹/PSU。现场测量支持了在实验室中发现的近红外和较短波长下的温度和盐度依赖性。为了估计我们未进行测量的波长区域中的温度依赖性,我们使用了一系列高斯曲线,这些曲线拟合到光谱可见光区域的吸收光谱上。然后根据将高斯曲线乘以拟合因子来估计光谱对温度的依赖性。