信函：单体钼（V）配合物在其电子顺磁共振光谱中显示出氢-1、氢-2和氮-14超超精细分裂。对钼酶的启示。 - Suppr | 超能文献

Letter: Monomeric molybdenum (V) complexes showing hydrogen-1, hydrogen-2, and nitrogen-14 superhyperfine splitting in their electron paramagnetic resonance spectra. Implications for molybdenum enzymes.

作者信息

Pariyadath N, Newton W E, Stiefel E I

出版信息

J Am Chem Soc. 1976 Aug 18;98(17):5388-90. doi: 10.1021/ja00433a055.

DOI:10.1021/ja00433a055

Abstract

摘要

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Comparison of the molybdenum centres of native and desulpho xanthine oxidase. The nature of the cyanide-labile sulphur atom and the nature of the proton-accepting group.天然型和脱硫型黄嘌呤氧化酶钼中心的比较。氰化物敏感硫原子的性质和质子接受基团的性质。

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