Navia Rodrigo, Bezama Alberto
Department of Chemical Engineering, University of La Frontera, Temuco, Chile.
J Hazard Mater. 2008 Oct 1;158(1):177-84. doi: 10.1016/j.jhazmat.2008.01.071. Epub 2008 Jan 31.
The new "Hazardous Waste Management Regulation" was published in the Official Newspaper of the Chilean Republic on 12 June 2003, being in force 365 days after its publication (i.e., 12 June 2004). During the next 180 days after its publication (i.e., until 12 December 2004), each industrial facility was obligated to present a "Hazardous Waste Management Plan" if the facility generates more than 12 ton/year hazardous wastes or more than 12 kg/year acute toxic wastes. Based on the Chilean industrial figures and this new regulation, hazardous waste management plans were carried out in three facilities of the most important sectors of Chilean industrial activity: a paper production plant, a Zn and Pb mine and a sawmill and wood remanufacturing facility. Hazardous wastes were identified, classified and quantified in all facilities. Used oil and oil-contaminated materials were determined to be the most important hazardous wastes generated. Minimization measures were implemented and re-use and recycling options were analyzed. The use of used oil as alternative fuel in high energy demanding facilities (i.e., cement facilities) and the re-refining of the used oil were found to be the most suitable options. In the Zn and Pb mine facility, the most important measure was the beginning of the study for using spent oils as raw material for the production of the explosives used for metals recovery from the rock. In Chile, there are three facilities producing alternative fuels from used oil, while two plants are nowadays re-refining oil to recycle it as hydraulic fluid in industry. In this sense, a proper and sustainable management of the used oil appears to be promissory.
新的《危险废物管理条例》于2003年6月12日在智利共和国官方报纸上公布,自公布之日起365天后生效(即2004年6月12日)。在公布后的接下来180天内(即至2004年12月12日),若工业设施每年产生超过12吨危险废物或超过12千克急性有毒废物,则必须提交一份“危险废物管理计划”。根据智利的工业数据和这项新规定,在智利工业活动最重要的三个部门的设施中实施了危险废物管理计划:一家造纸厂、一座锌铅矿以及一家锯木厂和木材再制造设施。对所有设施中的危险废物进行了识别、分类和量化。废油和受油污染的材料被确定为产生的最重要危险废物。实施了减量化措施,并分析了再利用和回收选项。发现在高能耗设施(如水泥设施)中使用废油作为替代燃料以及对废油进行再精炼是最合适的选择。在锌铅矿设施中,最重要的措施是开始研究将废油用作从岩石中回收金属所用炸药的生产原料。在智利,有三家设施用废油生产替代燃料,而如今有两家工厂对油进行再精炼以便作为工业液压油进行回收利用。从这个意义上讲,对废油进行恰当且可持续的管理似乎很有前景。