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功能化肼的合成：简便的均相（N-杂环卡宾）-钯（0）催化偶氮苯的双硼化和硅硼化反应

Synthesis of Functionalized Hydrazines: Facile Homogeneous (N-Heterocyclic Carbene)-Palladium(0)-Catalyzed Diboration and Silaboration of Azobenzenes.

作者信息

Ansell Melvyn B, Kostakis George E, Braunschweig Holger, Navarro Oscar, Spencer John

机构信息

Department of Chemistry University of Sussex Brighton BN1 9QJ U.K.

Institut für Anorganische ChemieJulius-Maximilians-Universität Würzburg Am Hubland 97074 Würzburg Germany; Institute for Sustainable Chemistry & Catalysis with Boron Julius-Maximilians-Universität Würzburg Am Hubland 970704 Würzburg Germany.

出版信息

Adv Synth Catal. 2016 Dec 7;358(23):3765-3769. doi: 10.1002/adsc.201601106. Epub 2016 Nov 9.

DOI:10.1002/adsc.201601106
PMID:28111537
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5215626/
Abstract

The bis(N-heterocyclic carbene)(diphenylacetylene)palladium complex [Pd(ITMe)(PhC≡CPh)] (ITMe=1,3,4,5-tetramethylimidazol-2-ylidene) acts as a highly active pre-catalyst in the diboration and silaboration of azobenzenes to synthesize a series of novel functionalized hydrazines. The reactions proceed using commercially available diboranes and silaboranes under mild reaction conditions.

摘要

双（N-杂环卡宾）（二苯乙炔）钯配合物[Pd(ITMe)(PhC≡CPh)]（ITMe = 1,3,4,5-四甲基咪唑-2-亚基）在偶氮苯的双硼化和硅硼化反应中作为一种高活性的预催化剂，用于合成一系列新型功能化肼。反应在温和的反应条件下使用市售的双硼烷和硅硼烷进行。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da07/5215626/4058b2b4e78a/ADSC-358-3765-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da07/5215626/c9c477c88b51/ADSC-358-3765-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da07/5215626/a243f77a2ef4/ADSC-358-3765-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da07/5215626/8610c4644713/ADSC-358-3765-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da07/5215626/4058b2b4e78a/ADSC-358-3765-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da07/5215626/c9c477c88b51/ADSC-358-3765-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da07/5215626/a243f77a2ef4/ADSC-358-3765-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da07/5215626/8610c4644713/ADSC-358-3765-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da07/5215626/4058b2b4e78a/ADSC-358-3765-g004.jpg

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