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Polyoxometalate embedding of a tetraruthenium(IV)-oxo-core by template-directed metalation of [gamma-SiW10O36]8-: a totally inorganic oxygen-evolving catalyst.

作者信息

Sartorel Andrea, Carraro Mauro, Scorrano Gianfranco, De Zorzi Rita, Geremia Silvano, McDaniel Neal D, Bernhard Stefan, Bonchio Marcella

机构信息

ITM-CNR and Department of Chemical Sciences, University of Padova, Via F. Marzolo 1, 35131 Padova, Italy.

出版信息

J Am Chem Soc. 2008 Apr 16;130(15):5006-7. doi: 10.1021/ja077837f. Epub 2008 Mar 18.

DOI:10.1021/ja077837f
PMID:18345628
Abstract

Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, gamma-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h-1.

摘要

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