Nie Zhihong, Kumacheva Eugenia
Department of Chemistry, University of Toronto, 80 Saint George Street, Toronto, Ontario M5S 3H6, Canada.
Nat Mater. 2008 Apr;7(4):277-90. doi: 10.1038/nmat2109.
The ability to pattern functional polymers at different length scales is important for research fields including cell biology, tissue engineering and medicinal science and the development of optics and electronics. The interest and capabilities of polymer patterning have originated from the abundance of functionalities of polymers and a wide range of applications of the patterns. This paper reviews recent advances in top-down and bottom-up patterning of polymers using photolithography, printing techniques, self-assembly of block copolymers and instability-induced patterning. Finally, challenges and future directions are discussed from the point of view of both applicability and strategies for the surface patterning of polymers.
在不同长度尺度上对功能聚合物进行图案化的能力,对于细胞生物学、组织工程、医学以及光学和电子学等研究领域以及相关领域的发展而言至关重要。聚合物图案化的吸引力和能力源于聚合物丰富的功能以及图案的广泛应用。本文综述了利用光刻、印刷技术、嵌段共聚物自组装和不稳定性诱导图案化等方法对聚合物进行自上而下和自下而上图案化的最新进展。最后,从聚合物表面图案化的适用性和策略两个角度讨论了面临的挑战和未来方向。