Ilardi Elizabeth A, Stivala Craig E, Zakarian Armen
Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390, USA.
Org Lett. 2008 May 1;10(9):1727-30. doi: 10.1021/ol800341z. Epub 2008 Apr 3.
Stereoselective preparation of iodoalkenes from vinylsilanes is described. 1,1,1,3,3,3-hexafluoroisopropanol serves as a unique solvent that ensures high yields and stereoselectivities in the iododesilylation of a variety of functionalized substrates.
描述了从乙烯基硅烷立体选择性制备碘代烯烃的方法。1,1,1,3,3,3-六氟异丙醇作为一种独特的溶剂，可确保各种官能化底物在碘代脱硅反应中具有高收率和立体选择性。
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