Van Wambeke E
Certis Europe B.V., Woluwedal 60, BE-1200 Brussels, Belgium.
Commun Agric Appl Biol Sci. 2007;72(2):61-70.
Almost no single commercially available or registered compound is able to replace the broad spectrum activity of methyl bromide. However, combinations of for long known fumigants or their generators, showing good activity in the control of specific groups of soil borne diseases or pests, show interesting broad spectrum activity and even synergism. Well-known combinations are 1,3-dichloropropene (1,3-D) and chloropicrin, applied by injection or through irrigation lines. A few decades ago, combination products containing 1,3-D and methyl isothiocyanate (MITC) were developed and commercialized but were not Longer supported. As 1,3-D is an excellent nematicide with other target groups depending on contact time and tarping, and dazomet as a MITC generator shows fungicidal, nematicidal, insecticidal and herbicidal activities, studies with combinations of both were started again. Laboratory trials with different combinations of 1,3-D and Basamid (97 % dazomet) in soil columns showed interesting results both with Basamid solved in 1,3-D, although limited by temperature, and with simultaneously applied products, even at half dose of each, or even tess. In a further stage, small greenhouse trials were performed with tomato and lettuce crop and could confirm synergistic activity through the evaluation of crop stand and harvest results. Other trial work was performed in collaboration between Certis Europe branches and local research groups in both Italy and Spain. There again it was demonstrated that the combination of 1,3-D (injectable as well as emulsifiable formulations) with Basamid are able to control different phytosanitary problems in different crops. In parallel with the above mentioned trial work, emphasis is also made on careful and appropriate tarping of the soil, preferentially by improved gastight barrier film. The latter allows dose reduction as well as improvement of the fumigation performance. Barrier properties of commercially available fumigation film are now studied for both 1,3-D and MITC. Finally, it is emphasized that appropriate application systems and machinery need more attention to achieve good results with this type of fumigants, i.e. less volatile and with less good diffusion capacity as compared to methyl bromide.
几乎没有任何一种市售或注册的化合物能够替代溴甲烷的广谱活性。然而,一些长期以来已知的熏蒸剂或其发生器的组合,在控制特定种类的土传病害或害虫方面表现出良好活性,显示出有趣的广谱活性甚至协同作用。著名的组合是1,3 - 二氯丙烯(1,3 - D)和氯化苦,通过注射或通过灌溉管道施用。几十年前,含有1,3 - D和甲基异硫氰酸酯(MITC)的组合产品被开发并商业化,但后来不再得到支持。由于1,3 - D是一种优良的杀线虫剂,对其他目标群体的作用取决于接触时间和覆盖,而棉隆作为一种MITC发生器具有杀菌、杀线虫、杀虫和除草活性,因此对两者的组合研究又重新开始。在土柱中对1,3 - D和必速灭(97%棉隆)的不同组合进行的实验室试验显示了有趣的结果,无论是将必速灭溶解在1,3 - D中(尽管受温度限制),还是同时施用这两种产品,即使每种剂量减半甚至更低剂量。在进一步的阶段,对番茄和生菜作物进行了小型温室试验,通过对作物生长状况和收获结果的评估,可以确认协同活性。其他试验工作是由Certis欧洲分公司与意大利和西班牙的当地研究小组合作进行的。在那里再次证明,1,3 - D(注射剂和乳油制剂)与必速灭的组合能够控制不同作物中的各种植物检疫问题。在进行上述试验工作的同时,还强调要对土壤进行仔细且适当的覆盖,优先使用改进的气密阻隔薄膜。后者可以减少剂量并提高熏蒸效果。目前正在研究市售熏蒸薄膜对1,3 - D和MITC的阻隔性能。最后,强调需要更加关注合适的施用系统和机械,以便使用这类熏蒸剂取得良好效果,即与溴甲烷相比挥发性更低且扩散能力较差的熏蒸剂。