Tanaka Ken, Komatsu Katsuko
Division of Pharmacognosy, Department of Medicinal Resources, Institute of Natural Medicine, University of Toyama, 2630 Sugitani, Toyama, 930-0194, Japan.
J Nat Med. 2008 Jan;62(1):112-6. doi: 10.1007/s11418-007-0199-7. Epub 2007 Oct 6.
Volatile components in 13 crude drug samples derived from Nardostachys chinensis or Nardostachys grandiflora were studied by solid phase micro extraction (SPME)-GC and SPME-GC-MS. Twenty-three compounds accounting for 81.3 and 70.0% of volatile components in newly collected samples of two species were identified. beta-Maaliene, 9-aristolene, calarene and patchouli alcohol were identified as the major volatile constituents of N. chinensis, whereas aromadendrene, cube-11-ene, epi-alpha-selinene, spirojatamol and valeranone were identified as those of N. grandiflora. Using the peaks of beta-maaliene and 9-aristolene in GC profiles as the marker, two Nardostachys species were clearly distinguished among the samples examined.
采用固相微萃取(SPME)-气相色谱(GC)和SPME-气相色谱-质谱联用(SPME-GC-MS)技术,对甘青青兰或大花甘青蓝根中的13个药材样品的挥发性成分进行了研究。在两个物种新采集样品中,鉴定出23种化合物,分别占挥发性成分的81.3%和70.0%。β-马兜铃烯、9-亚甲基环癸三烯、卡拉烯和广藿香醇被鉴定为甘青青兰的主要挥发性成分,而香树烯、11-立方烯、表-α-芹子烯、螺雅槛蓝醇和缬草酮则被鉴定为大花甘青兰的主要挥发性成分。以GC图谱中β-马兜铃烯和9-亚甲基环癸三烯的峰为标记,在所检测的样品中能够清晰地区分这两种甘青兰。