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通过吸附到由生物质材料制备的活性炭上从水溶液中去除苯酚。

Removal of phenol from aqueous solutions by adsorption onto activated carbon prepared from biomass material.

作者信息

Hameed B H, Rahman A A

机构信息

School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia.

出版信息

J Hazard Mater. 2008 Dec 30;160(2-3):576-81. doi: 10.1016/j.jhazmat.2008.03.028. Epub 2008 Mar 15.

Abstract

Activated carbon derived from rattan sawdust (ACR) was evaluated for its ability to remove phenol from an aqueous solution in a batch process. Equilibrium studies were conducted in the range of 25-200mg/L initial phenol concentrations, 3-10 solution pH and at temperature of 30 degrees C. The experimental data were analyzed by the Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models. Equilibrium data fitted well to the Langmuir model with a maximum adsorption capacity of 149.25mg/g. The dimensionless separation factor RL revealed the favorable nature of the isotherm of the phenol-activated carbon system. The pseudo-second-order kinetic model best described the adsorption process. The results proved that the prepared activated carbon was an effective adsorbent for removal of phenol from aqueous solution.

摘要

对由藤木屑衍生的活性炭(ACR)在间歇过程中从水溶液中去除苯酚的能力进行了评估。在初始苯酚浓度为25 - 200mg/L、溶液pH为3 - 10以及温度为30℃的范围内进行了平衡研究。通过朗缪尔、弗伦德利希、特姆金和杜比宁 - 拉杜舍维奇等温线模型对实验数据进行了分析。平衡数据与朗缪尔模型拟合良好,最大吸附容量为149.25mg/g。无量纲分离因子RL表明苯酚 - 活性炭体系等温线具有良好的性质。准二级动力学模型能最好地描述吸附过程。结果证明所制备的活性炭是从水溶液中去除苯酚的有效吸附剂。

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