Weinbruch Stephan, Dirsch Thomas, Ebert Martin, Hofmann Heiko, Kandler Konrad
Institute of Applied Geosciences, Technical University Darmstadt, Schnittspahnstr. 9, Darmstadt, 64287, Germany.
J Environ Monit. 2008 May;10(5):648-54. doi: 10.1039/b719344k. Epub 2008 Mar 26.
The use of hydrated magnesium carbonate hydroxide (magnesia alba) for drying the hands is a strong source for particulate matter in indoor climbing halls. Particle mass concentrations (PM10, PM2.5 and PM1) were measured with an optical particle counter in 9 indoor climbing halls and in 5 sports halls. Mean values for PM10 in indoor climbing halls are generally on the order of 200-500 microg m(-3). For periods of high activity, which last for several hours, PM10 values between 1000 and 4000 microg m(-3) were observed. PM(2.5) is on the order of 30-100 microg m(-3) and reaches values up to 500 microg m(-3), if many users are present. In sports halls, the mass concentrations are usually much lower (PM10 < 100 microg m(-3), PM2.5 < or = 20 microg m(-3)). However, for apparatus gymnastics (a sport in which magnesia alba is also used) similar dust concentrations as for indoor climbing were observed. The size distribution and the total particle number concentration (3.7 nm-10 microm electrical mobility diameter) were determined in one climbing hall by an electrical aerosol spectrometer. The highest number concentrations were between 8000 and 12 000 cm(-3), indicating that the use of magnesia alba is no strong source for ultrafine particles. Scanning electron microscopy and energy-dispersive X-ray microanalysis revealed that virtually all particles are hydrated magnesium carbonate hydroxide. In-situ experiments in an environmental scanning electron microscope showed that the particles do not dissolve at relative humidities up to 100%. Thus, it is concluded that solid particles of magnesia alba are airborne and have the potential to deposit in the human respiratory tract. The particle mass concentrations in indoor climbing halls are much higher than those reported for schools and reach, in many cases, levels which are observed for industrial occupations. The observed dust concentrations are below the current occupational exposure limits in Germany of 3 and 10 mg m(-3) for respirable and inhalable dust. However, the dust concentrations exceed the German guide lines for work places without use of hazardous substances. In addition, minimizing dust concentrations to technologically feasible values is required by the current German legislation. Therefore, substantial reduction of the dust concentration is required.
在室内攀岩馆中,使用氢氧化碳酸镁水合物(镁氧混合物)来擦干双手是颗粒物的一个重要来源。使用光学粒子计数器在9个室内攀岩馆和5个体育馆中测量了颗粒物质量浓度(PM10、PM2.5和PM1)。室内攀岩馆中PM10的平均值通常在200 - 500微克/立方米左右。在持续数小时的高活动时段,观测到PM10值在1000至4000微克/立方米之间。如果有很多使用者,PM2.5约为30 - 100微克/立方米,最高可达500微克/立方米。在体育馆中,质量浓度通常要低得多(PM10 < 100微克/立方米,PM2.5 < 或 = 20微克/立方米)。然而,对于器械体操(一种也使用镁氧混合物的运动),观测到的粉尘浓度与室内攀岩馆类似。通过电气溶胶光谱仪在一个攀岩馆中测定了粒径分布和总粒子数浓度(3.7纳米 - 10微米电迁移直径)。最高粒子数浓度在8000至12000立方厘米-3之间,表明使用镁氧混合物并非超细颗粒的重要来源。扫描电子显微镜和能量色散X射线微分析表明,几乎所有颗粒都是氢氧化碳酸镁水合物。在环境扫描电子显微镜中的原位实验表明,这些颗粒在相对湿度高达100%时不会溶解。因此,可以得出结论,镁氧混合物的固体颗粒会悬浮在空气中,并有可能沉积在人体呼吸道中。室内攀岩馆中的颗粒物质量浓度远高于学校报告的浓度,在许多情况下,达到了工业职业环境中观测到的水平。观测到的粉尘浓度低于德国目前对可吸入粉尘和可吸入性粉尘规定的职业接触限值3毫克/立方米和10毫克/立方米。然而,粉尘浓度超过了德国针对不使用有害物质的工作场所的指导标准。此外,德国现行法律要求将粉尘浓度降至技术上可行的值。因此,需要大幅降低粉尘浓度。