一种合成不对称硅酮缩醛的有效方法：用于闭环（包括大环闭环）复分解反应的底物。
An efficient method for synthesising unsymmetrical silaketals: substrates for ring-closing, including macrocycle-closing, metathesis.
作者信息
Cordier Christopher, Morton Daniel, Leach Stuart, Woodhall Thomas, O'Leary-Steele Catherine, Warriner Stuart, Nelson Adam
机构信息
School of Chemistry, University of Leeds, Leeds, UK, LS2 9JT.
出版信息
Org Biomol Chem. 2008 May 21;6(10):1734-7. doi: 10.1039/b804769n. Epub 2008 Apr 10.
Abstract
Diisopropylsilyl ethers were activated with N-bromosuccinimide, and reacted with a fluorous-tagged alcohol, to yield tethered substrates for ring-closing metathesis reactions.
摘要
二异丙基甲硅烷基醚用N-溴代琥珀酰亚胺活化，并与含氟标记的醇反应，生成用于闭环复分解反应的连接底物。
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