一种用于叠氮化物与炔烃的“点击”1,3-偶极环加成反应的高活性且可重复使用的铜（I）-三亚乙基四胺催化剂。
A highly active and reusable copper(I)-tren catalyst for the "click" 1,3-dipolar cycloaddition of azides and alkynes.
作者信息
Candelon Nicolas, Lastécouères Dominique, Diallo Abdou Khadri, Aranzaes Jaime Ruiz, Astruc Didier, Vincent Jean-Marc
机构信息
University Bordeaux-1, CNRS-UMR 5255, Institut des Sciences Moléculaires, 351 Cours de la libération, 33405 Talence, France.
出版信息
Chem Commun (Camb). 2008 Feb 14(6):741-3. doi: 10.1039/b716306a.
The copper(I) complex [Cu(C18(6)tren)]Br 1 (C18(6)tren = tris(2-dioctadecylaminoethyl)amine) which exhibits a good stability towards aerobic conditions is a versatile, highly reactive and recyclable catalyst for the Huisgen cycloaddition of azides with terminal or internal alkynes and is a useful catalyst for the preparation of "click" dendrimers.
铜（I）配合物[Cu(C18(6)tren)]Br 1（C18(6)tren = 三（2 - 二十八烷基氨基乙基）胺）对有氧条件具有良好的稳定性，是用于叠氮化物与末端或内炔烃的惠斯根环加成反应的通用、高活性且可循环使用的催化剂，也是制备“点击”树枝状大分子的有用催化剂。
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