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本文引用的文献

1
Cyclic (Alkyl)(amino)carbene Gold(I) complexes: A Synthetic and Structural Investigation.环状（烷基）（氨基）卡宾金（I）配合物：合成与结构研究。
J Organomet Chem. 2008 Apr;693(8-9):1674-1682. doi: 10.1016/j.jorganchem.2008.01.026.
2
Recent advances in organothorium and organouranium catalysis.有机钍和有机铀催化的最新进展。
Chem Soc Rev. 2008 Mar;37(3):550-67. doi: 10.1039/b614969n. Epub 2007 Dec 19.
3
The reaction mechanism of the hydroamination of alkenes catalyzed by gold(I)-phosphine: the role of the counterion and the N-nucleophile substituents in the proton-transfer step.金（I）-膦催化烯烃氢胺化反应的机理：抗衡离子和N-亲核取代基在质子转移步骤中的作用。
J Am Chem Soc. 2008 Jan 23;130(3):853-64. doi: 10.1021/ja073578i. Epub 2008 Jan 1.
4
New routes for the functionalization of P4.
Angew Chem Int Ed Engl. 2008;47(5):831-3. doi: 10.1002/anie.200704305.
5
Asymmetric hydroamination of non-activated carbon-carbon multiple bonds.非活化碳-碳多重键的不对称氢胺化反应
Dalton Trans. 2007 Nov 28(44):5105-18. doi: 10.1039/b711126f. Epub 2007 Sep 7.
6
Heterolytic H2 activation by nonmetals.
Angew Chem Int Ed Engl. 2008;47(1):38-41. doi: 10.1002/anie.200702816.
7
Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes.通过金催化的掩蔽卡宾与亚乙烯基的交叉偶联生成丙二烯。
Proc Natl Acad Sci U S A. 2007 Aug 21;104(34):13569-73. doi: 10.1073/pnas.0705809104. Epub 2007 Aug 13.
8
Selective palladium-catalyzed arylation of ammonia: synthesis of anilines as well as symmetrical and unsymmetrical di- and triarylamines.钯催化氨的选择性芳基化反应：苯胺以及对称和不对称二芳基胺与三芳基胺的合成。
J Am Chem Soc. 2007 Aug 29;129(34):10354-5. doi: 10.1021/ja074681a. Epub 2007 Aug 2.
9
The catalytic hydroamination of alkynes.
Chem Soc Rev. 2007 Sep;36(9):1407-20. doi: 10.1039/b600981f. Epub 2007 Mar 9.
10
Gold-catalyzed organic reactions.金催化的有机反应。
Chem Rev. 2007 Jul;107(7):3180-211. doi: 10.1021/cr000436x. Epub 2007 Jun 20.

Homogeneous catalytic hydroamination of alkynes and allenes with ammonia.

作者信息

Lavallo Vincent, Frey Guido D, Donnadieu Bruno, Soleilhavoup Michele, Bertrand Guy

机构信息

UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403, USA.

出版信息

Angew Chem Int Ed Engl. 2008;47(28):5224-8. doi: 10.1002/anie.200801136.

DOI:10.1002/anie.200801136
PMID:18528830
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2529152/
Abstract
摘要