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Rhodium-catalyzed regioselective C-H functionalization via decarbonylation of acid chlorides and C-H bond activation under phosphine-free conditions.铑催化的通过酰氯脱羰作用和在无膦条件下的C-H键活化实现的区域选择性C-H官能化反应。

J Am Chem Soc. 2008 Jul 2;130(26):8136-7. doi: 10.1021/ja803154h. Epub 2008 Jun 10.

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Efficient Rh(I)-catalyzed direct arylation and alkenylation of arene C-H bonds via decarbonylation of benzoic and cinnamic anhydrides.通过苯甲酸酐和肉桂酸酐的脱羰基反应实现铑（I）催化的芳烃C-H键高效直接芳基化和烯基化反应。

Org Lett. 2009 Mar 19;11(6):1317-20. doi: 10.1021/ol9000729.

3

Phosphine oxides as preligands in ruthenium-catalyzed arylations via C-H bond functionalization using aryl chlorides.在使用芳基氯化物通过C-H键官能化进行钌催化芳基化反应中作为前配体的氧化膦

Org Lett. 2005 Jul 7;7(14):3123-5. doi: 10.1021/ol051216e.

4

Palladium-pincer complex catalyzed C-C coupling of allyl nitriles with tosyl imines via regioselective allylic C-H bond functionalization.钯钳形配合物通过区域选择性烯丙基C-H键官能化催化烯丙基腈与甲苯磺酰亚胺的C-C偶联反应。

Org Lett. 2008 Jul 3;10(13):2881-4. doi: 10.1021/ol801070n. Epub 2008 Jun 5.

5

An efficient waste-free oxidative coupling via regioselective C-H bond cleavage: Rh/Cu-catalyzed reaction of benzoic acids with alkynes and acrylates under air.通过区域选择性C-H键裂解实现高效无废氧化偶联：苯甲酸与炔烃和丙烯酸酯在空气中的Rh/Cu催化反应

Org Lett. 2007 Mar 29;9(7):1407-9. doi: 10.1021/ol070406h. Epub 2007 Mar 9.

6

Palladium-catalyzed desulfitative Mizoroki-Heck couplings of sulfonyl chlorides with mono- and disubstituted olefins: rhodium-catalyzed desulfitative heck-type reactions under phosphine- and base-free conditions.钯催化磺酰氯与单取代和双取代烯烃的脱硫化 Mizoroki-Heck 偶联反应：在无膦和无碱条件下的铑催化脱硫化 Heck 型反应。

Chemistry. 2005 Apr 22;11(9):2633-41. doi: 10.1002/chem.200400838.

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Palladium-catalyzed C-H bond functionalization with arylsulfonyl chlorides.钯催化的与芳基磺酰氯的C-H键官能团化反应。

J Am Chem Soc. 2009 Mar 18;131(10):3466-7. doi: 10.1021/ja900200g.

8

Copper-catalyzed synthesis of benzoxazoles via a regioselective C-H functionalization/C-O bond formation under an air atmosphere.铜催化下在空气氛围中通过区域选择性C-H官能化/C-O键形成反应合成苯并恶唑类化合物。

J Org Chem. 2009 Jun 5;74(11):4272-7. doi: 10.1021/jo900513z.

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C-C, C-O and C-N bond formation via rhodium(III)-catalyzed oxidative C-H activation.通过铑(III)催化的氧化 C-H 活化实现 C-C、C-O 和 C-N 键的形成。

Chem Soc Rev. 2012 May 7;41(9):3651-78. doi: 10.1039/c2cs15281a. Epub 2012 Feb 29.

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Efficient functionalization of aromatic C-H bonds catalyzed by gold(III) under mild and solvent-free conditions.金（III）催化的芳族C-H键在温和且无溶剂条件下的高效官能团化反应。

J Org Chem. 2004 May 28;69(11):3669-71. doi: 10.1021/jo0497353.

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铑催化的通过酰氯脱羰作用和在无膦条件下的C-H键活化实现的区域选择性C-H官能化反应。

Rhodium-catalyzed regioselective C-H functionalization via decarbonylation of acid chlorides and C-H bond activation under phosphine-free conditions.

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