铑催化的通过酰氯脱羰作用和在无膦条件下的C-H键活化实现的区域选择性C-H官能化反应。
Rhodium-catalyzed regioselective C-H functionalization via decarbonylation of acid chlorides and C-H bond activation under phosphine-free conditions.
作者信息
Zhao Xiaodan, Yu Zhengkun
机构信息
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, Liaoning 116023, PR China.
出版信息
J Am Chem Soc. 2008 Jul 2;130(26):8136-7. doi: 10.1021/ja803154h. Epub 2008 Jun 10.
PMID:18540607
Abstract
Efficient rhodium(I)-catalyzed regioselective functionalization of aromatic C-H bonds has been realized with acid chlorides as the coupling partners via decarbonylation and C-H activation under phosphine-free conditions.
摘要
在无膦条件下，通过脱羰和C-H活化，以酰氯作为偶联伙伴，实现了铑（I）催化的芳族C-H键的高效区域选择性官能化。
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