Cambel Vladimír, Martaus Jozef, Soltýs Ján, Kúdela Robert, Gregusová Dagmar
Institute of Electrical Engineering, Slovak Academy of Sciences, Dúbravská cesta 9, 841 04 Bratislava, Slovakia.
Ultramicroscopy. 2008 Sep;108(10):1021-4. doi: 10.1016/j.ultramic.2008.04.032. Epub 2008 May 8.
The local anodic oxidation (LAO) by the tip of atomic force microscope (AFM) is used for fabrication of nanometer-scaled structures and devices. We study the technology of LAO applied to semiconductor heterostructures, theoretically and experimentally as well. The goal is to improve the LAO process itself, i.e., to create narrow LAO lines that form high-energy barriers in the plane with the 2D electron gas. In the first part we show the electric field distribution in the system tip-sample during LAO. For samples with low-conductive cap layer the maximum electric field is shifted apart the tip apex, which leads to wide oxide lines. Our Monte Carlo (MC) calculations show how the height of the energy barrier in the system depends on the geometry of the created lines (trenches), and on voltage applied to the structure. Based on the calculations, we have proposed a novel LAO technology and applied it to InGaP/AlGaAs/GaAs heterostructure with doping layer only 6 nm beneath the surface. The doping layer can be oxidized easily by the AFM tip in this case, and the oxide objects can be removed by several etchants. This approach to the LAO technology leads to narrow LAO trenches (approximately 60 nm) and to energy barriers high enough for room- and low-temperature applications.
利用原子力显微镜(AFM)针尖进行的局部阳极氧化(LAO)可用于制造纳米级结构和器件。我们从理论和实验两方面研究了应用于半导体异质结构的LAO技术。目标是改进LAO工艺本身,即创建在二维电子气平面中形成高能垒的窄LAO线。在第一部分中,我们展示了LAO过程中针尖 - 样品系统中的电场分布。对于具有低导电帽层的样品,最大电场偏离针尖顶点,这导致氧化线变宽。我们的蒙特卡罗(MC)计算表明系统中能垒的高度如何取决于所创建线条(沟槽)的几何形状以及施加到结构上的电压。基于这些计算,我们提出了一种新颖的LAO技术,并将其应用于表面下方仅6 nm处有掺杂层的InGaP/AlGaAs/GaAs异质结构。在这种情况下,掺杂层很容易被AFM针尖氧化,并且氧化物物体可以通过几种蚀刻剂去除。这种LAO技术方法可形成窄的LAO沟槽(约60 nm)以及足以用于室温及低温应用的高能垒。