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高比表面积竹基活性炭的制备与比较

Production and comparison of high surface area bamboo derived active carbons.

作者信息

Ip A W M, Barford J P, McKay G

机构信息

Department of Chemical Engineering, Hong Kong University of Science and Technology, Kowloon, Hong Kong.

出版信息

Bioresour Technol. 2008 Dec;99(18):8909-16. doi: 10.1016/j.biortech.2008.04.076. Epub 2008 Jun 24.

Abstract

High surface area activated carbons have been produced from the natural biomaterial bamboo, using phosphoric acid as the activating agent. The effects of phosphoric acid impregnation ratio, activation temperature, heating rate on the carbon surface area, porosity and mass yield are presented. Three of these bamboo derived active carbons, surface areas 1337, 1628 and 2123m(2)/g were assessed for their ability to adsorb Acid Red 18 dye from aqueous solution; these results were compared with three conventional adsorbents: activated carbon F400, bone char and peat. Isotherm data were analysed using Langmuir, Freundlich, Redlich-Peterson and Langmuir-Freundlich isotherms. Different isotherms provided the best fit correlations to the adsorption experimental data but the Langmuir-Freundlich equation provided the best overall correlation of data. The adsorption capacities of two of the selected bamboo derived carbons were much greater than the capacities of the other three adsorbents.

摘要

以磷酸为活化剂,采用天然生物材料竹子制备了高比表面积活性炭。研究了磷酸浸渍比、活化温度、升温速率对活性炭比表面积、孔隙率和质量产率的影响。对三种竹子衍生活性炭(比表面积分别为1337、1628和2123m²/g)从水溶液中吸附酸性红18染料的能力进行了评估;并将这些结果与三种传统吸附剂:活性炭F400、骨炭和泥炭进行了比较。使用朗缪尔、弗伦德里希、雷德利希-彼得森和朗缪尔-弗伦德里希等温线对等温线数据进行了分析。不同的等温线与吸附实验数据具有最佳拟合相关性,但朗缪尔-弗伦德里希方程对数据的整体相关性最佳。所选两种竹子衍生活性炭的吸附容量远大于其他三种吸附剂的吸附容量。

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