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染料对竹炭的吸附。

Dye adsorption onto char from bamboo.

机构信息

Department of Chemical & Biomolecular Engineering, Hong Kong University of Science & Technology, Clearwater Bay, Kowloon, Hong Kong SAR.

出版信息

J Hazard Mater. 2010 May 15;177(1-3):1001-5. doi: 10.1016/j.jhazmat.2010.01.018. Epub 2010 Jan 11.

Abstract

Experiments have been carried out to prepare char from waste bamboo scaffolding for wastewater treatment. Carbonisation parameters such as temperature, holding time, heating rate and particle size were investigated. When the material was heated to 1173 K for 2h, surface area S(BET-N(2)) and total pore volume (V(total)) were 327 m(2)/g and 0.185 cm(3)/g, respectively. Particle size and heating rate appear less influential to the yield and textural characteristics of the resultant chars. Bamboo char obtained in this study did not show very high adsorption capacities for two acid dyes (Acid Blue 25 and Acid Yellow 117) but exhibited significant uptake of Methylene Blue. The equilibrium data were modelled by three different isotherms, namely, Langmuir, Freundlich and Redlich-Peterson model. Comparing the predicted data using optimised parameters from each model based on the SSE error function, the Redlich-Peterson isotherm appears the 'best' model to correlate experimental data.

摘要

已经进行了实验,以准备从废竹脚手架为废水处理的炭。碳化参数,如温度,保持时间,加热速率和粒度进行了调查。当该材料加热到 1173 K 2 小时,表面积 S(BET-N(2))和总孔体积(V(总))分别为 327 m(2)/克和 0.185 cm(3)/克,分别。粒径和加热速率对产率和所得炭的结构特性的影响较小。在这项研究中获得的竹炭对两种酸性染料(酸性蓝 25 和酸性黄 117)并没有表现出非常高的吸附能力,但对亚甲蓝表现出显著的吸收。平衡数据用三种不同的等温线模型进行了模拟,即朗缪尔、弗伦德利希和 Redlich-Peterson 模型。比较了基于 SSE 误差函数从每个模型优化参数预测数据,Redlich-Peterson 等温线似乎是关联实验数据的“最佳”模型。

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