Kauffman Douglas R, Star Alexander
Department of Chemistry, University of Pittsburgh and The National Energy Technology Laboratory, Pittsburgh, PA, USA.
Angew Chem Int Ed Engl. 2008;47(35):6550-70. doi: 10.1002/anie.200704488.
Carbon nanotubes have aroused great interest since their discovery in 1991. Because of the vast potential of these materials, researchers from diverse disciplines have come together to further develop our understanding of the fundamental properties governing their electronic structure and susceptibility towards chemical reaction. Carbon nanotubes show extreme sensitivity towards changes in their local chemical environment that stems from the susceptibility of their electronic structure to interacting molecules. This chemical sensitivity has made them ideal candidates for incorporation into the design of chemical sensors. Towards this end, carbon nanotubes have made impressive strides in sensitivity and chemical selectivity to a diverse array of chemical species. Despite the lengthy list of accomplishments, several key challenges must be addressed before carbon nanotubes are capable of competing with state-of-the-art solid-state sensor materials. The development of carbon nanotube based sensors is still in its infancy, but continued progress may lead to their integration into commercially viable sensors of unrivalled sensitivity and vanishingly small dimensions.
自1991年被发现以来,碳纳米管引起了极大的关注。由于这些材料具有巨大的潜力,来自不同学科的研究人员齐聚一堂,以进一步加深我们对支配其电子结构和化学反应敏感性的基本特性的理解。碳纳米管对其局部化学环境的变化表现出极高的敏感性,这源于其电子结构对相互作用分子的敏感性。这种化学敏感性使其成为化学传感器设计中的理想候选材料。为此,碳纳米管在对多种化学物质的灵敏度和化学选择性方面取得了令人瞩目的进展。尽管取得了诸多成就,但在碳纳米管能够与最先进的固态传感器材料竞争之前,仍有几个关键挑战必须加以解决。基于碳纳米管的传感器的开发仍处于起步阶段,但持续的进展可能会使其集成到具有无与伦比的灵敏度和极小尺寸的商业可行传感器中。