Febrianto Jonathan, Kosasih Aline Natasia, Sunarso Jaka, Ju Yi-Hsu, Indraswati Nani, Ismadji Suryadi
Department of Chemical Engineering, National Taiwan University of Science and Technology, 43 Section 4, Keelung Road, Taipei 10607, Taiwan.
J Hazard Mater. 2009 Mar 15;162(2-3):616-45. doi: 10.1016/j.jhazmat.2008.06.042. Epub 2008 Jun 20.
Distinctive adsorption equilibria and kinetic models are of extensive use in explaining the biosorption of heavy metals, denoting the need to highlight and summarize their essential issues, which is the main purpose of this paper. As a general trend, up until now, most studies on the biosorption of heavy metal ions by miscellaneous biosorbent types have been directed toward the uptake of single metal in preference to multicomponent systems. In particular, Langmuir and Freundlich models are the most common isotherms for correlating biosorption experimental data though other isotherms, which were initially established for gas phase applications, can also be extended onto biosorption system. In kinetic modeling, the pseudo-first and -second order equations are considered as the most celebrated models.
独特的吸附平衡和动力学模型在解释重金属的生物吸附方面有广泛应用,这表明有必要突出并总结其关键问题,这也是本文的主要目的。总体而言,到目前为止,大多数关于各种生物吸附剂类型对重金属离子生物吸附的研究都倾向于单一金属的吸附,而非多组分体系。特别是,朗缪尔和弗伦德利希模型是关联生物吸附实验数据最常用的等温线,不过其他最初为气相应用建立的等温线也可扩展到生物吸附体系。在动力学建模中,拟一级和拟二级方程被认为是最著名的模型。