Whitby Max, Cagnon Laurent, Thanou Maya, Quirke Nick
Chemistry Department, Imperial College, South Kensington, London SW7 2AZ, United Kingdom.
Nano Lett. 2008 Sep;8(9):2632-7. doi: 10.1021/nl080705f. Epub 2008 Aug 5.
Recent experimental and theoretical studies demonstrate that pressure driven flow of fluids through nanoscale ( d < 10 nm) carbon pores occurs 4 to 5 orders of magnitude faster than predicted by extrapolation from conventional theory. Here, we report experimental results for flow of water, ethanol, and decane through carbon nanopipes with larger inner diameters (43 +/- 3 nm) than previously investigated. We find enhanced transport up to 45 times theoretical predictions. In contrast to previous work, in our systems, decane flows faster than water. These nanopipes were composed of amorphous carbon deposited from ethylene vapor in alumina templates using a single step fabrication process.
最近的实验和理论研究表明,流体在纳米级(d < 10 nm)碳孔中的压力驱动流动比从传统理论外推预测的速度快4到5个数量级。在此,我们报告了水、乙醇和癸烷在比先前研究内径更大(43 +/- 3 nm)的碳纳米管中流动的实验结果。我们发现传输增强高达理论预测的45倍。与先前的工作不同,在我们的系统中,癸烷比水流动得更快。这些纳米管由使用单步制造工艺从氧化铝模板中的乙烯蒸气沉积的非晶碳组成。