Felpin François-Xavier, Fouquet Eric
Université de Bordeaux, CNRS, Institut des Sciences Moléculaires, UMR 5255, 351 cours de la Libération, 33405 Talence, France.
ChemSusChem. 2008;1(8-9):718-24. doi: 10.1002/cssc.200800110.
The development of sustainable organometallic chemistry is one of the many challenges that chemists must address to solve environmental issues. Until now, the classical approach was to develop highly selective homogeneous catalysts for a single transformation. However, a new area of research focuses on the execution of two or more reactions in the same vessel using heterogeneous multitask catalysts. This approach results in a reduced number of operations leading to time and cost benefits. Moreover, owing to the scarcity of natural resources and the recent dramatic cost increase of these resources and metals, the development of recyclable heterogeneous catalysts is urgent. This Minireview focuses on the latest developments in tandem reactions promoted by heterogeneous multitask catalysts.
可持续有机金属化学的发展是化学家为解决环境问题必须应对的众多挑战之一。到目前为止,传统方法是开发用于单一转化的高选择性均相催化剂。然而,一个新的研究领域专注于使用多相多任务催化剂在同一容器中进行两个或更多反应。这种方法减少了操作步骤,从而节省了时间和成本。此外,由于自然资源的稀缺以及这些资源和金属最近的大幅成本上涨,开发可回收的多相催化剂迫在眉睫。本综述聚焦于多相多任务催化剂促进的串联反应的最新进展。