基于芪和α-环糊精的光驱动分子肌肉的基础。
The foundation of a light driven molecular muscle based on stilbene and alpha-cyclodextrin.
作者信息
Dawson Ryan E, Lincoln Stephen F, Easton Christopher J
机构信息
ARC Centre of Excellence for Free Radical Chemistry and Biotechnology, Research School of Chemistry, The Australian National University, Canberra, ACT 0200, Australia.
出版信息
Chem Commun (Camb). 2008 Sep 14(34):3980-2. doi: 10.1039/b809014a. Epub 2008 Jul 17.
DOI:10.1039/b809014a
PMID:18758599
Abstract
The rotaxane 3(E,E) serves as the basis of a light driven molecular muscle, where reversible photoisomerisation of the stilbene units causes the cyclodextrins to move off and on the stilbene units, contracting and extending the distance between the blocking groups.
摘要
轮烷3（E，E）用作光驱动分子肌肉的基础，其中芪单元的可逆光异构化使环糊精在芪单元上移动或离开，从而使阻断基团之间的距离收缩和伸展。
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