铜（I）催化的共轭二烯的不对称双胺化反应
Cu(I)-catalyzed asymmetric diamination of conjugated dienes.
作者信息
Du Haifeng, Zhao Baoguo, Yuan Weicheng, Shi Yian
机构信息
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
出版信息
Org Lett. 2008 Oct 2;10(19):4231-4. doi: 10.1021/ol801605w. Epub 2008 Sep 3.
Abstract
A Cu(I)-catalyzed asymmetric diamination for a variety of conjugated dienes and a triene with encouraging ee's has been effectively achieved using (R)-DTBM-SEGPHOS as a chiral ligand and di- tert-butyldiaziridinone as the nitrogen source.
摘要
使用(R)-DTBM-SEGPHOS作为手性配体、二叔丁基二氮杂环丁烷作为氮源，已有效地实现了铜(I)催化的多种共轭二烯和一种三烯的不对称双胺化反应，对映体过量值令人鼓舞。
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