Kim Ki-Heon, Chung Bong-Jin, Lee Sang-Hyeob, Seo Yong-Chil
National Institute of Environmental Research, Inchon, Republic of Korea.
Chemosphere. 2008 Nov;73(10):1632-9. doi: 10.1016/j.chemosphere.2008.07.068. Epub 2008 Sep 17.
This study strives to estimate the emission of dioxin and furthermore attempts to find the best technological control methods available for waste incinerators by investigating the emission status thereof. In order to incorporate the Stockholm Convention, a particular stringent law was promulgated in Korea and in recent years incinerators were forced to utilize better technological control. After the enforcement of special dioxin emission regulation in 2003, the average concentration of dioxin emitted from municipal and industrial waste incinerators decreased from 15.25 and 12.86 ng TEQ Nm(-3) to 5.53 and 4.96 ng TEQ Nm(-3) in 2001 and 2004, respectively. Based on test results at commercial plants, several best arranged sets of air pollution control devices (APCDs) were suggested in order to provide guidelines to help operators. These sets included combinations of spray dry absorbers, bag type filters, wet scrubbers, selective catalytic reductions and electrostatic precipitators. Different suggestions and real installations of APCD arrangement were investigated during the years around the regulation in effective. The results were presented depending on the capacity of the incinerators and different waste streams to observe the efforts to reduce dioxin emission by operators of incineration plants. The annual amount of dioxin emission from the incinerators is expected to be 212.5 g-TEQ in 2011 and 234.3g-TEQ in 2015, respectively, compared to 891.6g-TEQ recorded in 2001. The enforcement of new regulation and the installation of better APCDs showed the significant effect on such reduction. This reduction in dioxin emission from incinerators confirmed the nation's commitment to the regulatory requirement set by the Stockholm Convention.
本研究致力于估算二噁英的排放量,并通过调查垃圾焚烧炉的排放状况,尝试找出适用于垃圾焚烧炉的最佳技术控制方法。为了符合《斯德哥尔摩公约》,韩国颁布了一项特别严格的法律,近年来,焚烧炉被迫采用更好的技术控制措施。2003年实施特殊的二噁英排放法规后,城市和工业垃圾焚烧炉排放的二噁英平均浓度分别从2001年的15.25和12.86纳克毒性当量/立方米降至2004年的5.53和4.96纳克毒性当量/立方米。基于商业工厂的测试结果,提出了几套最佳的空气污染控制设备(APCD)组合,以便为操作人员提供指导。这些组合包括喷雾干燥吸收器、袋式过滤器、湿式洗涤器、选择性催化还原器和静电除尘器。在法规生效前后的几年里,对APCD配置的不同建议和实际安装情况进行了调查。根据焚烧炉的容量和不同的废物流呈现结果,以观察焚烧厂操作人员为减少二噁英排放所做的努力。预计2011年焚烧炉的二噁英年排放量分别为212.5克毒性当量,2015年为234.3克毒性当量,而2001年的记录为891.6克毒性当量。新法规的实施和更好的APCD的安装对这种减少产生了显著影响。焚烧炉中二噁英排放的减少证实了该国对《斯德哥尔摩公约》规定的监管要求的承诺。