Pajak T
Zakład Maszyn i Urzadzeń Energetycznych, Akademia Górniczo-Hutnicza, Kraków.
Rocz Panstw Zakl Hig. 1996;47(1):105-19.
Within the group of organochlorine, posing a positive danger the natural environment, the most interesting, controversial and objectionable for ecology++ are dioxins. In professional journals the name "dioxins" is a simplification which commonly refers to a certain group of organic chemical compounds, or, to be more precise, their derivatives called polychlorinated dibenzodioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs). The latest research has confirmed the existence of yet another group of similar character polybrominated and polyfluorinated. Though other sources of industrial dioxins emission exist their first and foremost sources are incineration processes, in particular the processes of municipal, hospital and other toxic and chemical waste incineration. The compounds mentioned above, but all their isomers--tetrachlorodibenzodioxin (TCDD), tetrachlorodibenzofuran (TCDF)--are highly toxic and lack of emission control may prove highly hazardous for health and natural environment. The paper discusses a number of issues connected with dioxin emission during incineration of solid and gaseous municipal waste. A balance of the transport of dioxins between their source (i.e. the waste), through the process of their incineration and recombination, to the final stage--their presence in solid and gaseous incineration products. Following that European legislature on dioxin emission is discussed together with the presentation of state-of-the-art installations for reducing the amount of dioxins in exhausted gasses. Most of the research has been based on author's own observations and research done while taking active part in operation of selected waste incineration plants. The remaining data have been gathered from reference papers on current experiments carried out in European waste incineration plants. Summing up, the paper maintains that the incineration of municipal waste in state-of-the-art installations conforming to emission norms does not endanger the natural environment with dioxins emitted in exhaust gasses. This danger is, however, present in the solid incineration products due to high concentration of dioxins there. Operators are fully aware of this fact and attempt to counteract it. The awareness of presence of dioxins emitted in the process of waste incineration should be decisive factor while choosing technology and installation, which fitted appropriate cleanup equipment will guarantee level of dioxin emission safe for the environment and conforming to the norms of dioxin emission.
在对自然环境构成实际危害的有机氯化合物中,对生态最具吸引力、最具争议且最令人反感的当属二噁英。在专业期刊中,“二噁英”这个名称是一种简化称呼,通常指的是某类有机化合物,或者更准确地说,是其衍生物,即多氯代二苯并二噁英(PCDDs)和多氯代二苯并呋喃(PCDFs)。最新研究证实还存在另一类具有相似特性的多溴代和多氟代化合物。尽管工业二噁英排放还有其他来源,但其首要来源是焚烧过程,特别是城市垃圾、医院垃圾以及其他有毒化学废物的焚烧过程。上述化合物及其所有异构体——四氯二苯并二噁英(TCDD)、四氯二苯并呋喃(TCDF)——都具有高毒性,缺乏排放控制可能对健康和自然环境造成极大危害。本文讨论了与城市固体和气体垃圾焚烧过程中二噁英排放相关的一系列问题。探讨了二噁英从其源头(即垃圾),经过焚烧和重新组合过程,到最终阶段——在固体和气体焚烧产物中的存在情况的迁移平衡。随后讨论了欧洲关于二噁英排放的立法,并介绍了用于减少废气中二噁英含量的先进装置。大部分研究基于作者自身的观察以及在参与特定垃圾焚烧厂运营期间所做的研究。其余数据则收集自欧洲垃圾焚烧厂当前进行的实验的参考文献。总之,本文认为,在符合排放规范的先进装置中焚烧城市垃圾,废气中排放的二噁英不会危害自然环境。然而,由于固体焚烧产物中二噁英浓度很高,这种危害在固体焚烧产物中是存在的。运营商充分意识到这一事实并试图加以应对。在选择技术和装置时,对垃圾焚烧过程中排放二噁英的认识应是决定性因素,配备适当净化设备的装置将确保二噁英排放水平对环境安全且符合二噁英排放规范。