Li Quanjun, Zhang Jingwei, Liu Bingbing, Li Ming, Liu Ran, Li Xianglin, Ma Honglei, Yu Shidan, Wang Lin, Zou Yonggang, Li Zepeng, Zou Bo, Cui Tian, Zou Guangtian
State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, PR China.
Inorg Chem. 2008 Nov 3;47(21):9870-3. doi: 10.1021/ic800758d. Epub 2008 Oct 7.
Single crystalline TiO2-B nanoribbons with high-density nanocavities were successfully synthesized via a simple hydrothermal route. The as-prepared TiO2-B nanoribbons exhibited a large Brunauer, Emmett, and Teller (BET) surface area of about 305 m(2)/g because of the high-density nanocavities inside the thin nanoribbons. Electrochemical measurements indicated that the TiO2-B nanoribbons with dense nanocavities showed discharge specific capacity higher than those of TiO2-B nanotubes and nanowires. It was found that the dense nanocavities have an important influence on the electrochemical lithium intercalation properties.
通过简单的水热法成功合成了具有高密度纳米腔的单晶TiO₂-B纳米带。由于细纳米带内部的高密度纳米腔，所制备的TiO₂-B纳米带表现出约305 m²/g的大比表面积。电化学测量表明，具有致密纳米腔的TiO₂-B纳米带的放电比容量高于TiO₂-B纳米管和纳米线。发现致密的纳米腔对电化学锂嵌入性能有重要影响。
